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- W2379903411 abstract "The poisoning effects of 11 nitrogen compounds on 5 different kinds of oils (Yumen heavy diesel oil, Fushun acid Washed light shale oil, cetane, decalin, etc.) were investigated, the main purpose being to study the poisoning mechanism of different classes of nitrogen compoands on different cracking feed stocks. The results indicate that the poisoning effect of the pyridine and pyrrole classes of nitrogen compounds on the cracking activity and selectivity of the above mentioned oils is similar to that found in our precious reports. However, there is no such independent and additive property between the poisoning effects of these two classes of nitrogen compounds as found before. The poisoning curves produced by these two classes are also different: the pyridine class causes exponential decrease in activitv while pyrrole causes linear decrease. Furthermore, the poisoning effect of the pyridine class on the cracking selectivity, as expressed by the carbon number distribution of cracked products, is different for shale oil and petroleum. On the basis of these results, a poisoning model involving two different kinds of active centers as well as two different kinds of poisoning mechanism is proposed. By means of this model, the main results found in this and previous reports can all he explained." @default.
- W2379903411 created "2016-06-24" @default.
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- W2379903411 date "1960-01-01" @default.
- W2379903411 modified "2023-09-25" @default.
- W2379903411 title "CATALYTIC CRACKING OF SHALE OIL IV. NITROGEN POISONING OF PETROLEUM, SHALE OIL AND SATURATED HYDROCARBON" @default.
- W2379903411 hasPublicationYear "1960" @default.
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