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- W2380116401 abstract "The block copolymer poly(methyl methacrylate)-block-poly(2-hydroxyethyl acrylate)(PMMA-bPHEA) was synthesized through two steps.Firstly,poly(methyl methacrylate) with single-capped chlorine(PMMA-Cl) was polymerized by reverse atom transfer radical polymerization(RATRP),using 2,2-azobisisobutyronitrile as an initiator,FeCl3 as the catalyst and PPh3 as the ligand.Then PMMA-Cl was used as a macroinitiator to initiate polymerization of 2-hydroxyethyl acrylate using FeCl2/PPh3 as the catalyst by atom transfer radical polymerization(ATRP) and well controlled PMMA-b-PHEA with narrow polydispersity of 1.32 was obtained.The block copolymer was characterized by GPC,FTIR,1 H NMR,DSC and TGA." @default.
- W2380116401 created "2016-06-24" @default.
- W2380116401 creator A5038146331 @default.
- W2380116401 date "2010-01-01" @default.
- W2380116401 modified "2023-09-28" @default.
- W2380116401 title "The synthesis and characterization of block copolymer PMMA-b-PHEA" @default.
- W2380116401 hasPublicationYear "2010" @default.
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