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- W2380360925 abstract "Both the catalyst system consisting of optically active ligand(1S,2S) -N-p-toluenesulfonyl-1,(2-diphenylethylenediamine) ((S,S)-TsDPEN),rhodium complex bis(cycloocta-1,5-diene)-μ,μ'-dichlorodirhodium [RhClC_8H_(12)]_2 and the catalyst system consisting of racemic ligand (±)-2,2'-diamino-1,1'-binaphthyl,rhodium complex bis(cycloocta-1,5-diene)-μ,μ'-dichlorodirhodium,chiral activator(1S,2S)-1,2-diphenyl ethylenediamine were used to catalyze the hydride transfer reductive reaction of acetophenone. The products were characterized and analyzed by gas chromatograph and polarimeter. The results showed that the ((S,S)-TsDPEN)/[RhClC_8H_(12)]_2 catalyst system catalyzed the reaction to give phenylethanol in 72.16% EE and 5.11% conversion of acetophenone; while the (±)-2,2'-diamino-1,1'-binaphthyl/[RhClC_8H_(12)]_2/((S,S)-DPEN) catalyst system catalyzed the reaction to give 1-phenylethanol in 16.7% EE and 42.84% conversion of acetophenone, the ((S,S)-TsDPEN)/[RhClC_8H_(12)]_2 catalyst system showed better stereoselectivity." @default.
- W2380360925 created "2016-06-24" @default.
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- W2380360925 date "2004-01-01" @default.
- W2380360925 modified "2023-09-25" @default.
- W2380360925 title "Application of the Catalysts Consisting of Optically Active Ligand, Racemic Ligand,Chiral Activator and Rhodium Complex in the Hydride Transfer Reductive Reaction of Acetophenone" @default.
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