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- W2380454925 abstract "Interactions between β-cyclodextrin(β-CD)and alkyl trimethyl ammonium bromides(CnBr,n= 8,12,14)in aqueous solutions were investigated with titration microcalorimetry at 298.15 K.No stable complexation was observed between β-CD and C8Br,while host-guest inclusion complexes of 1.1 stoichiometry were formed between β-CD and either of the other two CnBr with the apparent experiential stability constants being β1=1.09×103 dm3·mol-1,β1 =14.80×103 dm3·mol-1,respectively for n=12,14.All the complexation processes were proved to be both enthalpy and entropy beneficial and the standard enthalpy effect(ΔHo)decreases with elongation of the hydrophobic chain.The results were discussed in the light of the microstructure of the host and guest molecules." @default.
- W2380454925 created "2016-06-24" @default.
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- W2380454925 date "2007-01-01" @default.
- W2380454925 modified "2023-09-26" @default.
- W2380454925 title "Study on Host-Guest Complexation between β-Cyclodextrin and Alkyl Trimethyl Ammonium Bromides with Microcalorimetry" @default.
- W2380454925 hasPublicationYear "2007" @default.
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