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- W2380459629 abstract "The changes of solidification point and those of microscopic structure around solidification of n-hexadecane and methyl linoleate(ML)-hexadecane systems were studied by the molecular dynamics simulation.The studies showed that adding ML to n-hexadecane could lower the system′s solidification point(SP),and the SP decreased with the addition of ML.The head-to-end distance(L) of n-hexadecane was calculated.The results demonstrated that the distribution of L changed gradually from more disordered one in which most n-hexadecane chains were curving to more ordered one in which most chains were full-stretching as temperature lowered.This agrees with the thermodynamic principles which the system′s randomness decreases with the reduction of temperature.Since ML molecule owns two cis-double-bonds as well as an approximately blocked ester group,the n-hexadecane molecules around ML in mixed systems could still be curved even at lower temperature,which made the mixed system keep fairly low temperature fluidity." @default.
- W2380459629 created "2016-06-24" @default.
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- W2380459629 date "2011-01-01" @default.
- W2380459629 modified "2023-09-22" @default.
- W2380459629 title "Molecular Dynamics Simulation in Solidification Process of n-Hexadecane and Methyl Linoleate-Hexadecane Systems" @default.
- W2380459629 hasPublicationYear "2011" @default.
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