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- W2380852817 abstract "Properties of selenocystine self-assembled monolayers at gold electrode(SeCys SAMs/Au) and hexade-cyltrimethylammonium bromide(CTAB)-selenocystine self-assembled bilayers at a gold electrode(CTAB-SeCys SAMs/Au) were investigated by electrochemical and contact angle experiments.The electrochemical behavior of cytochrome c(Cyt c) on SeCys SAMs/Au and CTAB-SeCys SAMs/Au electrodes are discussed.We show that SeCys and CTAB-SeCys can promote the redox reaction of Cyt c on these electrodes.The promoting effect of CTAB-SeCys is stronger than of SeCys.We found that the current of the redox reaction of Cyt c increased when the concentration of CTAB increased from 1×10-5 to 1×10-4 mol.L-1.The maximum current was observed when the concentration was close to the critical micelle concentration(cmc) of CTAB.The redox peaks of Cyt c on the CTAB-SeCys SAMs/Au electrode are 0.305 and 0.235 V,respectively and the electrochemical behavior is diffusion controlled.The promoting effect of SeCys was found to be due to a combination of SeCys and remnant group of lysine in Cyt c." @default.
- W2380852817 created "2016-06-24" @default.
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- W2380852817 date "2009-01-01" @default.
- W2380852817 modified "2023-09-25" @default.
- W2380852817 title "Electrochemical Reaction of Cytochrome c at Selenocystine Self-assembled Monolayers Modified Electrodes" @default.
- W2380852817 hasPublicationYear "2009" @default.
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