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- W2380914836 abstract "The unusual anodic peak emerging on negative potential scan for copper in concentrated NaOH media was investigated by X ray diffraction, X ray photoelectron spectroscopy techniques, potentiodynamic scan, galvanostatic reduction and fast triangular voltage methods. The results show that CuO is formed on the electrode at potentials above this unusual peak A 2,3 , but also produced at peak A 2,3 when copper has been beforehand anodized at high potentials. Longer pre oxidation time and higher pre oxidation potential are advantageous to the formation of CuO at peak A 2,3 . It is presented that the pent up growth of oxide layer in the high potential region occurs at the interface between metal and oxide by the field assisted migration of O 2- ions to electrode, and when potential negatively shifts to the range of peak A 2,3 , the O 2- (or cation vacancies) accumulated in the film could move towards the solution and combine with Cu 2+ ions at the interface between oxide and solution.[" @default.
- W2380914836 created "2016-06-24" @default.
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- W2380914836 date "2000-01-01" @default.
- W2380914836 modified "2023-09-25" @default.
- W2380914836 title "Unusual anodic peak on negative potential scan for copper in alkaline media" @default.
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