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- W2381123655 abstract "The La17Fe3Mn5Al2Ni73-xBx(x=0,1,3,5) hydrogen storage alloys were prepared using a vacuum induction-quenching furnace.The structure analysis showed that the alloy without adding boron were composed of LaNi5 phase and La2Ni7 phase,and the alloys doped with boron were composed of LaNi5 phase,La2Ni7 phase and La3Ni13B2 phase.With the increase of boron content in alloys,the LaNi5 phase and La2Ni7 phase decreased and the La3Ni13B2 phase increased gradually.The electrochemical testing showed that the activation property and the maximum discharge capacity of the alloys declined and the cyclic stability was improved when the boron content increased.The high rate dischargeability(HRD) of the alloy electrodes increased firstly and then decreased with increasing the boron content in alloys,which indicated that it is favorable for improving the high rate dischargeability of the alloy electrodes when the boron content was appropriate in alloys.With the increase of boron content in alloys,the exchange current density(I0) increased firstly and then decreased and the diffusion coefficient(D) of hydrogen in alloy bulk increased gradually,which indicated that the charge-transfer ability on the surface of alloys was the main controlling factor for the dynamics ability." @default.
- W2381123655 created "2016-06-24" @default.
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- W2381123655 date "2013-01-01" @default.
- W2381123655 modified "2023-09-27" @default.
- W2381123655 title "Influence of Boron on Structural and Electrochemical Properties of La_(17)Fe_(76)B_7-Type Hydrogen Storage Alloy" @default.
- W2381123655 hasPublicationYear "2013" @default.
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