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- W2381311603 abstract "The synthesis of diphenyl toluene dicarbamate from urea, toluene diamine and phenol is a complex reaction system. On the basis of the analysis for similar reaction system, four possible reaction pathways for synthesizing diphenyl toluene dicarbamate via urea route were proposed. The fundamental thermodynamic data of components in this reaction system were calculated by several methods of group contribution. The reaction enthalpy, Gibbs free energy change and equilibrium constant of all the reactions of the four possible reaction pathways were obtained. According to the results of thermodynamic calculation and experimental data in literature, the feasibility and difficulty of each reaction pathway were discussed. The results show that a better reaction pathway is urea reaction with phenol to give phenyl carbamate and then phenyl carbamate interacting with toluene diamine to form diphenyl toluene dicarbamate. The results from thermodynamic calculation and analysis can provide a theoretical basis for the experimental study and process development of the reaction." @default.
- W2381311603 created "2016-06-24" @default.
- W2381311603 creator A5087401813 @default.
- W2381311603 date "2015-01-01" @default.
- W2381311603 modified "2023-09-28" @default.
- W2381311603 title "Thermodynamic analysis on synthesis of diphenyl toluene dicarbamate via urea route" @default.
- W2381311603 hasPublicationYear "2015" @default.
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