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- W2381858580 abstract "Reaction of complex Ni[S2P(OCH2CH2PH)2]2 with nitrogen base donor 1,10-phenanthroline(phen) was carried out in petroleum ether and acetone solution to give green nitrogen base adduct 1,10-phenanthroline bis(O,O'-di(2-phenylethyl)dithiophosphato)nickel(II),Ni[S2P(OCH2CH2Ph)2]2·phen.The adduct was characterized by elemental analysis,UV–visible and IR spectra,thermal analysis and single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group P21/c with a = 1.0987(9) nm,b = 2.1432(9) nm,c=1.9025(5) nm,β = 98.68(1)°,V = 4.429(4) nm3,Z = 4,Dc = 1.370 Mg/m3,F(000) = 1904,μ = 0.743mm-1,the final R = 0.057 and wR = 0.1492 for 3498 observed reflections(I(2σ(I)).The Ni(Ⅱ) atom adopts a distorted octahedral geometry with four sulfur atoms from two O,O'-di(2-phenylethyl)dithiophosphate ligands and two nitrogen atoms from a phen ligand.The Ni-S distances rang from 0.2474(2) to 0.2505(17) nm,and the Ni-N distances are 0.2081(4) and 0.2090(5) nm.The overall structure of adduct consists of 1D chain-pair and 1D double-stranded helical chain,which formed from intermolecular π-π stacking,C-H…O and C-H…S hydrogen-bonding interactions.They are further extended to 3D supramolecular network via C-H…O hydrogen-bonding interactions." @default.
- W2381858580 created "2016-06-24" @default.
- W2381858580 creator A5036602170 @default.
- W2381858580 date "2011-01-01" @default.
- W2381858580 modified "2023-09-27" @default.
- W2381858580 title "Synthesis and Crystal Structure of 1,10-Phenanthroline Bis(O,O'-di(2-phenylethyl) dithiophosphato)Nickel(II)" @default.
- W2381858580 hasPublicationYear "2011" @default.
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