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- W2381985087 abstract "The purpose of this paper is to improve the yield of hydrolysis by the crystal structural change of cellulose based on chemical modification.A new 1,3,5-triazine derivative 2,4-dichloro6-phenoxyl-1,3,5-triazine(PHCT) was synthesized from phenol and 2,4,6-trichloro-1,3,5-triazine(TCT).The structure of PHCT was characterized with FT-IR and LC-MS spectra.Microcrystalline cellulose(MCC) was chemically modified with PHCT and the modified MCC was hydrolyzed to study the impact of the amount of PHCT on the crystal structure and the hydrolysis property of cellulose.The hydrolysis of the modified cellulose was carried on in the sulfur acid of which the concentration was 8%,at the temperature of 130℃ and with the duration of 5 hours.The yield of the reducing sugar is about 23%,which is the highest in the present study,as the relative molar percentage of PHCT in cellulose(by the cellulosic glucose ring) is 16.67%.The wide X-ray diffractometer spectra show that the crystalline structure of cellulose is changed a lot by chemical modification,which is considered being beneficial for the hydrolysis of cellulose." @default.
- W2381985087 created "2016-06-24" @default.
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- W2381985087 date "2013-01-01" @default.
- W2381985087 modified "2023-09-24" @default.
- W2381985087 title "Synthesis and Hydrolysis of Phenoxy Triazine Dichloride Modified Cellulose" @default.
- W2381985087 hasPublicationYear "2013" @default.
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