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- W2382091255 abstract "Thermosensitive P(NIPAM-co-NMAM)-g-(PLLA-g-MAAH) graft copolymers were synthesized via a free radical polymerization route using 2,2'-azobisisobutyronitrile(AIBN) as an initiator and 2- aminoethanethiol hydrochloride(AET·HCl) as a chain transfer agent.The structure,molecular weight and polydispersity of the copolymer were characterized by NMR,FTIR and GPC.The morphologies,size and size distribution of the as-synthesized copolymer micelles were investigated by TEM and DLS.The thermosensitive behavior and micellization were examined with UV-vis and surface tension measurements.The experimental results showed that the as-synthesized P(NIPAM-co-NMAM)-g-(PLLA-g-MAAH) copolymers formed sphere-like micelles in aqueous solution,with an average size of approximate 20 nm,a low critical solution temperature of about 42℃,and a critical micelle concentration of ca.28 mg/L.MTT assay indicated that the copolymers had no cytotoxicity or slight toxicity,and could be used as a potential biomedical material." @default.
- W2382091255 created "2016-06-24" @default.
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- W2382091255 date "2010-01-01" @default.
- W2382091255 modified "2023-09-24" @default.
- W2382091255 title "Synthesis,characterization and micelle behavior of thermosensitive P(NIPAM-co-NMAM)-g-(PLLA-g-MAAH) graft copolyrners" @default.
- W2382091255 hasPublicationYear "2010" @default.
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