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- W2382604105 abstract "The oxidation of medical wastewater in supercritical water was investigated experimentally in a batch reactor.The results show that the COD removal rate of medical wastewater obviously increases with the increases of reaction time and temperature rise;whereas it scarcely changes with pressure in the range of 25-27 MPa.Both MnSO4 and CuSO4 are active catalysts for COD removal rate of the wastewater,and CuSO4 offers greater influence when reaction time is less than 7 min.Ammonia-nitrogen mass concentration has no evident variation under various reaction conditions.The experimental data under the conditions of 420-480 ℃,25 MPa,and oxidant stoichiometric ratio 300% were used to fit the rate of reaction in a non-linear regression analysis,with the parameter values determined as follows: activation energy(170.025±11.692)kJ/mol,pre-exponential factor(4.98±0.01)×108 min-1·mg-0.918·L0.918 and reaction order of wastewater(based on COD) 1.918±0.256,and the confidence level of such kinetics modeling is 93%.Based on the enthalpy changes of the reaction mediums,the reaction heat of the medical wastewater in supercritical water oxidation(SCWO) was studied.The results indicate that the reaction heat is 296.63 kJ/kg when the organics are completely oxidized." @default.
- W2382604105 created "2016-06-24" @default.
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- W2382604105 date "2011-01-01" @default.
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- W2382604105 title "Experimental research on medical wastewater disposal by supercritical water oxidation" @default.
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