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- W2382720038 abstract "The title complex [Cu(NTB)Cl]ClO4 2.5 CH3OH(NTB = Tris(benzimidazolyl-2-methyl) amine) has been synthesized and characterized by UV-Vis.,elemental analysis,cyclic voltammetry and single crystal X-ray diffraction analysis.Polyphenol oxidase activities toward pyrogallol and catechol have been studied spectroscopically.Their kinetics obey the Michaelis-Menten equation.The turnover numbers of the complex toward pyrogallol are 88.2 h-1 and 0.54 h-1 for catechol at pH 8.0 and 30 ℃.Compared with the kinetic data,it is apparent that pyrogallol oxidation is easier than catechol,and catalytic activities increase with increasing of pH values." @default.
- W2382720038 created "2016-06-24" @default.
- W2382720038 creator A5081080106 @default.
- W2382720038 date "2008-01-01" @default.
- W2382720038 modified "2023-09-25" @default.
- W2382720038 title "Synthesis,Crystal Structure and Polyphenol Oxidase Activities Study of [Cu(NTB)Cl]ClO_4·2.5CH_3OH" @default.
- W2382720038 hasPublicationYear "2008" @default.
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