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- W2382856554 abstract "The rare-earth-based AB_5-type Mm(NiMnSiAl)_(4.3)Co_(0.6-x)Fe_x(x=0,0.1,0.2,0.3,0.4,0.5,0.6) hydrogen storage alloys were prepared by casting and rapid quenching.The microstructures of the as-cast and quenched alloys were analysed by XRD,SEM and TEM,and electrochemical characteristics of the as-cast and quenched alloys were measured.The effects of substituting Co with Fe on microstructures and electrochemical characteristics of the as-cast and quenched alloys were investigated in detail.The obtained results show that the effects of substituting Co with Fe on the phase structures of the as-cast and quenched alloys are imperceptible,but its effects on electrochemical characteristics of the alloys are notable.The discharge capacities decrease,but the cycle lives of the alloys were improved with the increase of the amount of Fe substitution.Especially,substituting Co with Fe can significantly enhance the cycle lives of the as-quenched alloys.The effect of substituting Co with Fe on the activation capability of the alloys was negligible,and the as-cast and quenched alloys can been completely activated through 2～4 charge-discharge cycles." @default.
- W2382856554 created "2016-06-24" @default.
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- W2382856554 date "2005-01-01" @default.
- W2382856554 modified "2023-09-23" @default.
- W2382856554 title "Effects of substituting Co with Fe on the microstructures and electrochemical performances of the as-cast and quenched AB_5-type hydrogen storage alloys" @default.
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