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• W2382914894 abstract "Abstract Reactions of CuCl, CuCl2 and CuBr2 with 1,3,5-tri-tert-butyl-1,3,5-triazacyclohexane (tBu3tach) resulted in the formation of [(tBu3tach-H)+(CuCl2)] (1), [(tBu3tach)(CuCl2)] (2) and [(tBu3tach-H)+(CuBr2)] (3) respectively. Interestingly, CuBr was found to mediate the cleavage of the C–N bonds of tBu3tach in a vast range of solvents, namely, chloroform, dichloromethane, tetrahydrofuran, acetonitrile and methanol to yield [Cu4Br4(tBuNCH2)4] (4) and stands as an example of C–N bond cleavage of 1,3,5-triazacyclohexane rings by copper salts. Compounds 1 and 3 contains amidinium cations and are unstable in solution towards the release of copper. The release of copper from 3 in solution was confirmed by the isolation of the compound, [CuBr(MeCN)] (5). Formation of the amidinium cations [(tBu3tach-H)+] in 1 and 3 may be avoided by the use of PPh3 to yield [(tBu3tach)Cu(PPh3)](PF6) (6), while the coordinated N-tert-butylmethanimine (tBuNCH2) in 4 could be replaced by PPh3 to yield [Cu4Br4(PPh3)4] (7). Complexes 1–7 are characterized by a combination of single crystal X-ray structure determination and/or elemental analysis, NMR, IR, and UV–Vis spectroscopy, and Mass spectrometry." @default.
• W2382914894 created "2016-06-24" @default.
• W2382914894 creator A5059698938 @default.
• W2382914894 creator A5087760384 @default.
• W2382914894 date "2016-09-01" @default.
• W2382914894 modified "2023-09-26" @default.
• W2382914894 title "Cleavage of carbon–nitrogen bond in 1,3,5-tri-tert-butyl-1,3,5-triazacyclohexane by copper(I) bromide" @default.
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• W2382914894 doi "https://doi.org/10.1016/j.molstruc.2016.05.027" @default.
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