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- W2382930518 abstract "The heterolytic and homolytic N-NO bond dissociation energies of seven N-nitrosoindole derivatives were evaluated by using titration calorimetry and relative thermodynamic cycles.The energetic scales of the heterolytic and homolytic N-NO bond dissociation energies of N-nitrosoindoles cover the ranges from 206.1 to 246.2 kJ/mol and from 119.1 to 124.6 kJ/mol,respectively,which indicates that N-nitrosoindoles are much easier to release a NO radical(NO5) rather than a NO cation(NO+).The estimation of the heterolytic and homolytic(N-NO)-5 bond dissociation energies of the N-nitrosoindoles radical anions gives the energetic ranges from 25.5 to 33.4 kJ/mol and from 5.0 to 40.5 kJ/mol for the(N-NO)-5 bond homolysis and heterolysis,respectively,which means that N-nitrosoindole radical anions are unstable at room temperature." @default.
- W2382930518 created "2016-06-24" @default.
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- W2382930518 date "2007-01-01" @default.
- W2382930518 modified "2023-09-23" @default.
- W2382930518 title "Determination of N—NO Bond Dissociation Energies of N-Nitrosoindoles and Their Radical Anions in Acetonitrile" @default.
- W2382930518 hasPublicationYear "2007" @default.
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