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- W2382998334 abstract "The single crystals of the title compound were obtained from a reaction of MnCO3, benzenetetracarboxylic acid (H4BTC) and imidazole in an aqueous solution. The crystal of Mn(II) complex (C28H34Mn2N12O124H2O, Mr = 912.62) belongs to tricli nic, space group P?with a = 10.036(1), b = 10.650(1), c = 11.102(1) , a = 114.72(2), b = 95.75(1), g = 108.46(2)o, V = 984.2(2) 3, Z = 1, Dc = 1.540 g/cm3, F(000) = 472, m(MoKa) = 0.726 mm-1, R = 0.0409 and wR = 0.1166 for 3909 observed reflections (I 2s(I)). The crystal consists of the polymeric Mn(II) complex anions and discrete Mn(II) complex cations, both with normal octahedral coordination geometry. Each BTC bridges two Mn(II) atoms to form the anionic polymeric chain, and the cations distribute be- tween the chains and link them through both classic and weak CH…O H-bonding." @default.
- W2382998334 created "2016-06-24" @default.
- W2382998334 creator A5075426616 @default.
- W2382998334 date "2004-01-01" @default.
- W2382998334 modified "2023-09-26" @default.
- W2382998334 title "Structure of a Polymeric Mn(II) Complex Bridged by Benzenetetracarboxylate" @default.
- W2382998334 hasPublicationYear "2004" @default.
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