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- W2383393485 abstract "A H-2S solid oxide fuel cell with a configuration of H_2S, (MoS_2+NiS+Ag)/Li_2SO_4+Al-2O-3/(NiO+Ag), air was fabricated and studied for production of power and for desulfurization of a fuel gas process stream. The cell was run at typical temperatures (600～650 ℃) and ambient pressure. The electrochemical performance of a fuel cell can be limited by electrolyte membrane formula, electrode materials and operating temperatures. The Li-2SO-4-based proton-conducting membrane incorporating Al-2O-3 and little boric (H-3BO-4) enhances mechanical and electrical properties, improves the membrane compactivity and cell performance. The suitable formula of Li-2SO-4 to Al-2O-3 is 3～4:1 by weight, and the suitable boric amount added is 2%～5% (wt), respectively. Composite anodes based on metal sulfides with Ag powder and electrolyte behaved well and stably in H-2S stream, and composite cathodes based mainly on nickel oxide with Ag powder and electrolyte had superior performance to Pt catalyst for removal of H-2S. The maximum power density of up to 70 mW·cm+{-2} and current density of as high as 180 mA·cm+{-2} were obtained at 650 ℃. However, the long-term cell stability remains to be investigated." @default.
- W2383393485 created "2016-06-24" @default.
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- W2383393485 date "2005-01-01" @default.
- W2383393485 modified "2023-09-22" @default.
- W2383393485 title "Investigation of H_2S Solid Oxide Fuel Cells with a Li_2SO_4-based Proton-conducting Membrane" @default.
- W2383393485 hasPublicationYear "2005" @default.
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