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- W2383420157 abstract "Equilibrium hydrogen dissociation pressure was measured as a function of composition and temperature for the samarium-hydrogen system in the range of 448 to 623 K. Relative partial enthalpies and entropies in the composition region of continuous solution from n=2 to 2.5atoms H/atom Sm have been evaluated from van't Hoff plots.The interaction energy between hydrogen atoms and octahedral interstices is negative(4~8kJ/mol)indicating attractive interaction.The rel-ative molar enthalpy and entropy of formation of of hydrogen-deficient hexagonal SmH_3 have been to the extreme high-purity conditions,the hysteresis found in this work is 6. 5 times less than that found in the past." @default.
- W2383420157 created "2016-06-24" @default.
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- W2383420157 date "1995-01-01" @default.
- W2383420157 modified "2023-09-25" @default.
- W2383420157 title "THERMODYNAMIC PROPERTIES OF S_m -H_2 SYSTEM" @default.
- W2383420157 hasPublicationYear "1995" @default.
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