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- W2384045623 abstract "In order to enhance the water and solvents resistance of polyurethane acrylate composite emulsion,a novel cationic fluorinated polyacrylate modified polyurethane composite emulsion was prepared via phase inversion solution polymerization with hydroxypropyl acrylate(HPA) and dodecylfluoroheptyl acrylate(DFHA) as starting monomers in the medium of polyurethane(PU) solution with azobisisobutyronitrile(AIBN) as initiator for free radical formation.Then the co-polymerized product was further reacted with N-methyldiethanolamine(NDMDEA) to extend its hydrophilic chain.The structure,particle morphology as well as chemical composition and hydrophobicity of the film surface of the targeted composite emulsion was characterized and examined by Infrared spectrum(IR),X-ray photoelectron spectroscopy(XPS),transmission electron microscope(TEM) and the contact angle determination instrument.Results indicated that fluorinated chain block is incorporated into the macro molecule chain of the polymer successfully.The composite emulsion has a stable core-shell structure.The interface composed of fluorinated acrylate(FA) chain blocks are formed on the film surface and the incorporation of FA blocks increase the contact angle between PUA film and water from 65° to 98°." @default.
- W2384045623 created "2016-06-24" @default.
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- W2384045623 date "2010-01-01" @default.
- W2384045623 modified "2023-09-23" @default.
- W2384045623 title "Synthesis and performance of cationic fluorinated polyacrylate modified polyurethane composite emulsion" @default.
- W2384045623 hasPublicationYear "2010" @default.
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