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- W2384104148 abstract "The electrochemical behaviors of irreversibly adsorbed antimony on Pt electrode and the processes of adsorption and oxidation of 1,2-propanediol on Pt/Sb_(ad) electrodes were studied by using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The results demonstrated that the Sb adatoms are stable on Pt electrode when the electrode potentials are below 0.50V(SCE) and the saturation coverage of Sb_(ad) is 0.34. It proved that various coverages of Sb_(ad) can be easily obtained by stripping partially Sb_(ad) starting from a saturation adsorbed Pt/ Sb_(ad) surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for 1,2-propanediol oxidation. In contrast to Pt electrodes, the oxidation peak current of 1,2-propanediol in this case twice increased. The EQCM studies provided quantitative results of surface mass variation during 1,2-propanediol oxidation, and have thrown new light on elucidating effects of adatom Sb_(ad) on Pt electrode surface towards 1, 2-propanediol oxidation." @default.
- W2384104148 created "2016-06-24" @default.
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- W2384104148 date "2003-01-01" @default.
- W2384104148 modified "2023-09-22" @default.
- W2384104148 title "Adsorption of Sb on Pt Electrodes and Effect on Oxidation of 1, 2-Propanediol" @default.
- W2384104148 hasPublicationYear "2003" @default.
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