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- W2384202207 abstract "Cellulose acetate (DS=1.4) was firstly prepared by hydrolyzing cellulose diacetate (DS=2.4) in the presence of glacial acetic acid using concentrated sulfuric acid as catalyst,and then a novel graft copolymer was obtained from ring-opening copolymerization of e-caprolactone with cellulose acetate using Sn(Oct)_2 as initiator.Effects of the purity of reactants,feed ratio,molar ratio of initiator to monomer,reaction time and reaction temperature on monomer conversion (C%),graft ratio (G%) and graft efficiency (GE%) were investigated.When the weight ratio of e-caprolactone to cellulose acetate is 4∶1,molar ratio of Sn(Oct)_2 to e-caprolactone is 0.005,and the graft polymerization was carried out at 140 ℃ for 16 h,C%,G%,GE% could approach 46.8%,65.2% and 122.1% respectively." @default.
- W2384202207 created "2016-06-24" @default.
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- W2384202207 date "2004-01-01" @default.
- W2384202207 modified "2023-09-23" @default.
- W2384202207 title "Study of the Graft Polymerization of ε-Caprolactone onto Cellulose Acetate" @default.
- W2384202207 hasPublicationYear "2004" @default.
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