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- W2384474564 abstract "The reactivities and selectivities in the methane partial oxidation reactions over three catalysts of 1%Rh/m-Sm_2O_3,1%Rh/γ-Al_2O_3,1%Rh/c-Sm_2O_3 have been compared in this study.The basicity of these different supports has been measured by temperature programmed desorption of carbon dioxide in a mass spectrometer.The rates of isotope exchange reactions(CH_4-D_2 and(16)￣O_2─(18)￣O_2) were used to measure the ability of activation of both C─H and O─O bonds of the reactants.he lack of direct correlation between the rates of methane con version and support’s basicity as well as ability of the scission of C─H and O─O bonds indicates that the effect of support on reactivity and selectivity is fairly complicated." @default.
- W2384474564 created "2016-06-24" @default.
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- W2384474564 date "1995-01-01" @default.
- W2384474564 modified "2023-10-07" @default.
- W2384474564 title "Methane Partial Oxidation to Synthesis GasII.Support Effect" @default.
- W2384474564 hasPublicationYear "1995" @default.
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