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- W2384528698 abstract "In order to improve the overcharge tolerance of Li-ion batteries,diphenyl ether as additive of overcharge short-circuit of Li-ion batteries was studied.Experimental results show that diphenyl ether can be electro-oxidized at around 4.5 V(vs.Li/Li+)on Pt plate electrode in the organic electrolyte of Li-ion battery,and the polymer with excellent electrochemical activity is formed.Diphenyl ether has no obvious detrimental effect on the positive electrode material until 4.25 V by the LiMn2O4 powder microelectrode.The result of simulated LiMn2O4/Li cell shows that when the overcharge voltage reaches around 4.5 V,the cell voltage will not increase;at the same time,diphenyl ether is found to be electo-polymerized on the positive electrode from the observation of scanning electron microscope.Moreover,the produced H+ during polymerizing is reduced to H2 on the negative electrode,the internal pressure of batteries is raised,so the safety of Li-ion battery can be improved by activating safety valve." @default.
- W2384528698 created "2016-06-24" @default.
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- W2384528698 date "2008-01-01" @default.
- W2384528698 modified "2023-09-27" @default.
- W2384528698 title "Additive of overcharge short-circuit for Li-ion battery" @default.
- W2384528698 hasPublicationYear "2008" @default.
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