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- W2384735380 abstract "The effects of the addition of 2.38×10-2 to 2.86×10-2 M AIBN and 8.8×10-2 to 6.1×10-4 M six substituted hydroxylamines, such as, N,N-diethlhydroxylamine (DEHA), N,N'-diisopro-pylhydroxylamine (DIPHA), N-hydroxyl-mofpholine ; (MPHA), 2,2,6,6-tetramethyl-4-hydro xyl-piperidinehydroxylamine (TMHPHA), N-phenylhydroxylamine (PHA) and N,N'-diph-enylhydroxyamine (DPHA) at 60℃ on the bulk polymerization of vinyl acetate (VAC) and .acrylonitrile (AN) has been studied respectively. The results showed that all six hydroxylamines exhibited inhibiting properties. The effect is more pronounced for VAC than for AN. At die same time the chain transfer constants (Ct) of these compounds in bulk polymerization of VAC and AN has been calculated respectively by Mayo equation. The result demonstrated that the G value for VAC in bulk polymerization is larger than that of AN under same condition. These differences not only depend on the structure of six hydroxylamines and the nitroxide radical derved from them in reaction, but also on the electron-donating or electronaccepting properties of monomers used and radicals formed." @default.
- W2384735380 created "2016-06-24" @default.
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- W2384735380 date "1990-01-01" @default.
- W2384735380 modified "2023-09-25" @default.
- W2384735380 title "INHIBITING EFFECT OF RADICAL POLYMERIZATION FOR VINYL MONOMERS XI.Studies on the Inhibition and Their Chain Transfer Constants of Substituted Hydroxylamine Compounds in Bulk Polymerization of Vinyl Acetate and Acrylonitrile" @default.
- W2384735380 hasPublicationYear "1990" @default.
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