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- W2384990357 abstract "An investigation into the organic permselective separation through poly(1-trimethylsilyl-1-propyne) (PTMSP) and (1-trimethylsilyl)-1-(1-penta-methyl-disilyl)-1-propyne copolymer(TMSP-PMDSP) dense membranes was made to gain an insight into the effect of the chemical structure of membrane materials on pervaporation (PV) characteristics. The results show that the copolymer has a higher separation factor α O/W but with a relatively lower value of flux J (g·m -2 ·h -1 ) than pure PTMSP. This phenomenon may be attributed to the introduction of side chains with large bulk volume in copolymer, which brought about a decrease of excess free volume and the improvement of diffusion selectivity to some extent. The copolymer membrane showed good performance for separating 1 37wt% dichloromethane/water liquid mixture at 35?℃ and 100 Pa ; the selectivity increased to 1?684.7 while the value of flux was about 336.0?g·m -2 ·h -1 ." @default.
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- W2384990357 date "2001-01-01" @default.
- W2384990357 modified "2023-10-08" @default.
- W2384990357 title "Organic permselective pervaporation characteristics of poly(silylpropyne) and copolymer dense membranes" @default.
- W2384990357 hasPublicationYear "2001" @default.
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