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- W2385306436 abstract "The identity SN2(C),SN2(N),SN2(Si) and SN2(P) reactions with Cl-have been investigated by an ab initio calculation method. Studies indicate that the activation energies of the back-attack and front-attack title reactions are affected by polarization and electronegativity of the central atom to a certain degree. The stronger the ability of polarization of the central atoms is,the lower the activation energy of the title reactions is,and the title reaction proceeds more easily. And the larger the electronegativity of the central atom is,the higher the activation energy of the title reactions is,and the title reaction proceeds difficultly." @default.
- W2385306436 created "2016-06-24" @default.
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- W2385306436 date "2013-01-01" @default.
- W2385306436 modified "2023-09-26" @default.
- W2385306436 title "Theoretical study on S_N2(C),S_N2(N),S_N2(Si) and S_N2(P) reactions with Cl~- in the gas phase" @default.
- W2385306436 hasPublicationYear "2013" @default.
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