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- W2385586509 abstract "Abstract Lilac pigments were prepared within the solid solution series Ba 0.5 Sr 0.5 Zn 2−x Ni x Si 2 O 7 with 0.1≤x≤0.5 from the corresponding oxides and carbonates via solid-state reactions. Depending on the composition, the solid solutions exhibit the crystal structure of the low-temperature and the high-temperature phases of BaZn 2 Si 2 O 7 . This structural change leads to a change in the optical spectra, i.e. the coloration of the ceramic powders. The different colors are attributed to the variation of the coordination sites of Ni 2+ . In the case of samples with the structure of HT-BaZn 2 Si 2 O 7 , Ni 2+ -ions are incorporated into tetrahedrally coordinated sites. Spectra of samples with the crystal structure of LT-BaZn 2 Si 2 O 7 are attributed to a mixture of Ni 2+ in tetrahedral coordination but also to distorted sites with higher coordination numbers." @default.
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- W2385586509 date "2016-08-01" @default.
- W2385586509 modified "2023-10-16" @default.
- W2385586509 title "Lilac ceramic pigments based on Ba 0.5 Sr 0.5 Zn 2−x Ni x Si 2 O 7 solid solutions" @default.
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- W2385586509 doi "https://doi.org/10.1016/j.ceramint.2016.05.082" @default.
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