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- W2385771660 abstract "We determined the time-averaged and space-averaged structures of supersaturated aqueous sodium pentaborate solutions by rapid liquid X-ray diffractometry at 298 and 323 K.Difference radial distribution functions(DRDF) and their theoretical partial radial distribution functions for B-B,B-O,O-O,Na-O and Na-B atom pairs were obtained from accurate diffraction data.The effects of concentration and temperature on the structure of the solutions were also discussed.Three main species(B3O3(OH)4-,B5O6(OH)4-and B(OH)3) were found to exist in supersaturated aqueous sodium pentaborate solutions and their hydrated structures were determined by model design and quantitative calculations.Higher temperature and higher concentration result in higher polyborates.As the concentration decreases,interaction distances and the average coordination number of the octahedral hexahydrated Na+ ion hardly changes while the hydration number of the polyborate increases.In concentrated solutions,the terminal-oxygen of the polyborates connects with the hydrated Na+ in a monodentate form to produce a contact ion pair with a characteristic distance of 0.328 nm." @default.
- W2385771660 created "2016-06-24" @default.
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- W2385771660 date "2010-01-01" @default.
- W2385771660 modified "2023-09-23" @default.
- W2385771660 title "Structure of Supersaturated Aqueous Sodium Pentaborate Solution" @default.
- W2385771660 hasPublicationYear "2010" @default.
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