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- W2385905123 abstract "A series of temperature-sensitive microgels were synthesized using N-isopropylacrylamide(NIPAM) as main monomer,tert-butyl acrylate(tBA) as comonomer,and N,N′-methylene-bis(acrylamide)(MBA) as cross-linking agent by modified surfactant-free emulsion polymerization method.The chemical structure and global shape with excellent monodispersity of the microgels were confirmed by FT-IR and SEM,respectively.The volume phase transition temperatures of P(NIPAM-co-tBA) microgels can be turned over a broad range by the incorporated amount of tBA comonomer,but their temperature-sensitivity decreases with the increase of the content of tBA units incorporated into the microgel network.The swelling ratios of P(NIPAM-co-tBA) microgels are lowered gradually by increasing tBA unit content within the microgel network because tBA units enhanced the hydrophobicity of P(NIPAM-co-tBA) copolymer chains." @default.
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- W2385905123 date "2006-01-01" @default.
- W2385905123 modified "2023-09-25" @default.
- W2385905123 title "Temperature-Sensitivity of Microgels Prepared by the Copolymerization of N-Isopropylacrylamide and Tert-Butyl Acrylate" @default.
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