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- W2386151991 abstract "In the paper,activated carbon was modified by methanol liquid,methanol vapor and supercriticalmethanol fluid;we prepared Ru/C catalyst using the modified activated carbon as the carrier by soaking in waterwith equal volume,studied the effects of different modification methods on the pore structure and the content ofsurface groups of the modified activated carbon by N2physical adsorption,Boehm titration,IR spectroscopy,SEM,XPS and so on,and evaluated the performance of the Ru/C catalyst based on the model reaction of glucosehydrogenation for preparing sorbitol.The results showed that the methanol vapor could only remove the ashes onthe surface of activated carbon;the supercritical methanol fluid not only could remove the ashes on the surface ofactivated carbon,but also could effectively reduce the content of oxygen-containing acidic groups so as to enhancethe interaction between the carrier and the active component Ru,thereby enhancing the electron binding energy ofRu and improving the activity of Ru/C catalyst.Under the conditions of temperature 393 K and hydrogen pressure4.0 MPa,the highest reaction rate of the catalyst was 46.51 mmol·min-1·g-1,which was 0.63 times higher thanthat before the modification." @default.
- W2386151991 created "2016-06-24" @default.
- W2386151991 creator A5034763632 @default.
- W2386151991 date "2011-01-01" @default.
- W2386151991 modified "2023-09-28" @default.
- W2386151991 title "EFFECT OF ACTIVATED CARBON MODIFIED BY METHANOL OF DIFFERENT CONDITIONS ON THE SURFACE PROPERTIES AND THE CATALYTIC PERFORMANCE OF Ru/C CATALYST FOR GLUCOSE HYDROGENATION" @default.
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