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- W2386202299 abstract "Two new binuclear complexes,[M2L2(phen)2(H2O)2](M=Zn,1;Co,2),assembled by 4-carboxymethoxy phenylacetic acid(H2L) and 1,10-phenanthroline(phen),have been synthesized under hydrothermal conditions.Single-crystal X-ray diffraction reveals complex 1 and 2 are isostructural,crystallized in monoclinic system,P21/c space group.The metal ion center is six-coordinated in a distorted octahedral geometry.Two neighboring center metal ions are linked together by two bridging L ligands forming a binuclear cage second building units(SBUs),and the SBUs are further linked to form 1D chain through intermolecular hydrogen bonds.In addition,π-π stacking interactions between the phen rings of the adjacent chains result in a 2D layer.The luminescence of complex 1 has also been investigated,and the result reveals that it displays luminescent property in the voilet region." @default.
- W2386202299 created "2016-06-24" @default.
- W2386202299 creator A5033179806 @default.
- W2386202299 date "2011-01-01" @default.
- W2386202299 modified "2023-09-25" @default.
- W2386202299 title "Hydrothermal Syntheses,Crystal Structures and Luminescent Properties of Binuclear Zn(II) and Co(II) Complexes Assembled by 4-Carboxymethoxy Phenylacetic Acid" @default.
- W2386202299 hasPublicationYear "2011" @default.
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