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- W2386366558 abstract "Two new lanthanide MOF compounds, [Nd2(bpdc)3(H2O)2]·bpy·4H2O (1) and [La2(bpdc)3(H2O)4]·4H2O (2) (bpdc=2,2′-bipyridine-3,3′-dicarboxylate, bpy=4,4′-bipyridine) have been synthesized under hydrothermal conditions. The crystal structure analysis indicates that both compounds crystallize in monoclinic system, space group C2/c. the crystal cell parameters for compound 1 are a=3.310 4(7) nm, b=0.748 12(15) nm, c=1.984 8(4) nm, β=104.75(3)°, and for compound 2 are a=2.674 9(5) nm, b=0.711 65(14) nm, c=2.054 2(4) nm, β=92.70(3)°. In compound 1, the Nd (Ⅲ) ions are bridged by bpdc ligands with two coordination modes to form a twodimensional neodymium MOF layer. The layers are connected by one-dimensional water chains and bpy molecules through rich hydrogen-bonding interactions to build up a three-dimensional supramolecular structure. The crystal structure of 2 is constructed by the layered lanthanum MOFs and the interlayer water chains through hydrogen bonding interactions." @default.
- W2386366558 created "2016-06-24" @default.
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- W2386366558 date "2010-01-01" @default.
- W2386366558 modified "2023-09-25" @default.
- W2386366558 title "Hydrothermal Synthesis and Crystal Structure of Two Novel Lanthanide MOF Compounds with One-Dimensional Water Chains" @default.
- W2386366558 hasPublicationYear "2010" @default.
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