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- W2386406574 abstract "At a concentration of 0-1.0 mol·L~(-1) the effect of salts(KCI,MgCI_2,and CaCI_2) on the structure of water was studied from the viewpoint of energy change using differential scanning calorimetry(DSC) and the results were compared with that obtained by the analysis of the chemical shift obtained by ~(17)O-NMR(δ(~(17)OH_2)).A linear increase in theδ(~(170OH_2) of water and a linear decrease in the apparent activation energy(-E'/R) of water with an increase in the concentration of salt was obtained.In addition, the rate of change ofδ(~(17)OH_2) and -E'IR increased as follows:KCIMgCI_2CaCI_2.Based on a two-state model,we demonstrate that the change inδ(~(17)OH_2) of water(△δ) is proportional to the change in molar energy of water(△E).These results indicate that KCI,MgCI_2,and CaCI_2 promote the formation of the water cluster structure and the energy change of water is equivalent to the chemical shift obtained by ~(17)O-NMR for the characterization of the water cluster structure." @default.
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- W2386406574 date "2011-01-01" @default.
- W2386406574 modified "2023-09-27" @default.
- W2386406574 title "Energy Characterization of Effect for Ions on the Structure of Water" @default.
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- W2386406574 doi "https://doi.org/10.3866/pku.whxb20111102" @default.
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