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- W2386521035 abstract "In order to mimic the active center of the V-HPOs,we designed and synthesized a series of oxovanadium complexes containing poly(pyrazolyl)borate ligands: VO(HB(3,5-Me2pz)3)(3,5-Me2pz)(HOOCCH2CH2COO)(1) and VO(HB(3,5-Me2pz)3)(3,5-Me2pz)(C5H4N-COO)(2),which were characterized by X-ray single crystal diffraction.Based on the characteristics that vanadium(Ⅴ) complexes catalyze phenol red oxidation of bromide into bromophenol blue in a water system under weak-acid condition,the study on ca-talytic activity about scorpionate oxovanadium(Ⅳ) complexes was preformed.The result shows that the scor-pionate oxovanadium(Ⅳ) complexes exhibit catalytic activity to the extent under the similar conditions.The mechanism of the catalytic reaction was analyzed by molecular orbital theory." @default.
- W2386521035 created "2016-06-24" @default.
- W2386521035 creator A5062875713 @default.
- W2386521035 date "2011-01-01" @default.
- W2386521035 modified "2023-09-23" @default.
- W2386521035 title "Synthesis,Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes" @default.
- W2386521035 hasPublicationYear "2011" @default.
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