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- W2386896445 abstract "The reasons for carbon deposition over Ni/Al 2O 3 catalyst in partial oxidation of CH 4 to syngas were studied with temperature-programmed mass spectrometry on-line analysis. The results showed that, the Ni xC formed from CH 4 decomposition can transform firstly to a kind of carbon species (so-called transition carbon), which can react with O 2 at 700 ℃ but cannot react with CO 2 even at 800 ℃. At high temperature, the transition carbon species then transforms to graphite, and the higher the temperature is, the faster the transforming rate is. The main carbon species deposited on the catalyst in partial oxidation of CH 4 to syngas is graphite from Ni xC, not reacting with oxygen, which will affect the activity of the catalyst and even lead to deactivation. Adding appropriate assistants to improve the reactivity of Ni xC with oxygen will restrain the formation of graphite." @default.
- W2386896445 created "2016-06-24" @default.
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- W2386896445 date "2001-01-01" @default.
- W2386896445 modified "2023-09-23" @default.
- W2386896445 title "Studies on the Reasons for Carbon Deposition over Ni/Al_2O_3 Catalyst in Partial Oxidation of CH_4 to Syngas with TPO Technique" @default.
- W2386896445 hasPublicationYear "2001" @default.
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