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- W2387665968 abstract "Two new trinuclear copper(Ⅱ) complexes bridged with N,N′ Bis(2 pyridylmethyl) Dithiooxamidate, [Cu 3L 2](ClO 4) 2(1) and [Cu 3L 2](NO 3) 2(2) (H 2L=N,N′ Bis(2 pyridylmethyl) Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV visible spectra, conductance and EPR spectra The variable temperature magnetic susceptibility for complex (1) has been measured in the range of 1 5 ̄298K Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator: H=-2J(S 1S 2+S 2S 3)-2J′S 1S 3, S 1=S 2=S 3=1/2 , giving the magnetic exchange parameters of 2 J =-170 cm -1 and 2 J ′=-7 2 cm -1 This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu(Ⅱ) ions" @default.
- W2387665968 created "2016-06-24" @default.
- W2387665968 creator A5045079312 @default.
- W2387665968 date "1999-01-01" @default.
- W2387665968 modified "2023-09-25" @default.
- W2387665968 title "SYNTHESIS AND CHARACTERIZATION OF TRINUCLEAR COPPER(II) COMPLEXES BRIDGED WITH N,N′ Bis(2 PYRIDYLMETHYL) DITHIOOXAMIDATE" @default.
- W2387665968 hasPublicationYear "1999" @default.
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