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- W2387790817 abstract "The catalytic properties of a series NiO/γ-Al2O3 catalysts doped with alkali and alkaline earth metals for the tri-reforming of methane were investigated and these catalysts were characterization with temperature programmed reduction(TPR) and temperature programmed desorption(TPD) techniques.It was shown that the doping of potassium improved CH4 and CO2 conversions,while the additions of other metals only benefit the conversion of CO2.At 750℃,CH4 and CO2 conversions of K-NiO/γ-Al2O3 catalyst reached 86.5% and 57.29%,and exceeded to those of NiO/γ-Al2O3(74.3% and 10.39%),respectively.The doping of alkali and alkaline earth metals increased the number of total basic centers and improved the adsorption capacity of CO2.The modification of K2O increased the content of weak bonding NiO species,stabled the free NiO species and increased the numbers of strong basic centers and active sites." @default.
- W2387790817 created "2016-06-24" @default.
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- W2387790817 date "2011-01-01" @default.
- W2387790817 modified "2023-09-22" @default.
- W2387790817 title "Effect of metal on catalytic performance of NiO/γ-Al_2O_3 for tri-reforming of methane" @default.
- W2387790817 hasPublicationYear "2011" @default.
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