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- W2387924418 abstract "Activity of four iron oxide catalysts,prepared by solid grinding method,sol-gel method,precipitation method and molysite forced hydrolysis method,respectively,for synthesis of dimethyl carbonate(DMC) through alcoholysis of urea,was investigated.The experimental results showed that iron oxide catalyst prepared by precipitation method had better catalytic activity.And the optimal preparation conditions on synthesis of dimethyl carbonate by urea and methanol were as follows: the molar ratio of methanol/urea was 65,the catalyst amount per 68mL methanol was 0.1g,the reaction temperature was 500 ℃,the reaction time was 7 h.The reaction mechanism is studied,and we believe the synthesis of dimethyl carbonate with Fe2O3 catalyst is the result of methanol and urea all being activated with Lewis's acidic metal oxides." @default.
- W2387924418 created "2016-06-24" @default.
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- W2387924418 date "2011-01-01" @default.
- W2387924418 modified "2023-09-24" @default.
- W2387924418 title "Preparation process of iron oxide catalyst for synthesis of DMC by alcoholysis of urea" @default.
- W2387924418 hasPublicationYear "2011" @default.
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