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- W2388032231 abstract "1,3-bis(4-hydroxyphenyl)adamantane-based polysulfones(ADPFS,ADPCS)were synthesized from 1,3-(4-hydroxyphenyl)adamantane(DPAD)and 4,4-difluorodiphenyl sulfone(DFDPS)or 4,4-dichlorodiphenyl sulfone(DCDPS)via solution polycondensation reaction.Adamantane-bisphenol A-based polysulfone(ADPFAS)was synthesized from DPAD,DFDPS and 2,2-bis(4-hydroxyphenyl)propane(BPA)by the same method.GPC test shows that the number average molecular weight of ADPFS and ADPCS is 41000 and 6600,respectively.The highly active monomer(4,4-difluorodiphenyl sulfone)is beneficial to synthesis of adamantane-based polysulfones with high molecular weigh.Thermal analysis reveals that the initial thermal decomposition temperature(410 ℃)of these adamantane-based polysulfones is similar to that of commercial polysulfones.However,the glass transition temperatures of ADPFS and ADPFAS are found to be 235 ℃ and 210 ℃,respectively,which are higher than that of the reported commercial polysulfone(186 ℃)significantly." @default.
- W2388032231 created "2016-06-24" @default.
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- W2388032231 date "2010-01-01" @default.
- W2388032231 modified "2023-09-23" @default.
- W2388032231 title "Synthesis and Properties of Adamantane-Based Polysulfones" @default.
- W2388032231 hasPublicationYear "2010" @default.
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