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- W2388408894 abstract "Irradiation of a mixture of enamines and α-bromo ketones, with a catalytic amount of Ir(ppy)3 by visible light (λ = 450 nm), enables the production of various 2,5-diaryl-substituted pyrroles in good to excellent yields. The key intermediates in this reaction have been identified as alkyl radicals, generated from single-electron transfer from the photoexcited Ir(ppy)3* to α-bromo ketones, which subsequently react with a broad range of enamines to undergo the Hantzsch reaction rapidly at ambient conditions." @default.
- W2388408894 created "2016-06-24" @default.
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- W2388408894 date "2016-05-11" @default.
- W2388408894 modified "2023-10-14" @default.
- W2388408894 title "Visible Light Initiated Hantzsch Synthesis of 2,5-Diaryl-Substituted Pyrroles at Ambient Conditions" @default.
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- W2388408894 doi "https://doi.org/10.1021/acs.orglett.6b01059" @default.
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