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- W2388423556 abstract "Degradation of cationic red GTL by heterogeneous photo-Fenton system using Ce-Fe/Al2O3 as catalyst was studied.The effects of initial concentration of H2O2,catalyst loading,initial pH value and various processes on degradation were investigated.The intermediates and final products during the reaction were detected by UV-vis absorption spectrography,ion chromatography and gas chromatography-mass spectrography.Degradation pathways and mechanism of cationic red GTL were discussed.The results show that cationic red GTL with stable structures can be degraded by heterogeneous photo-Fenton system.92.40% of total organic carbon(TOC) removal ratio is achieved at pH=6.0,20 ℃ of reaction temperature,90 min of reaction time,2 g/L of catalyst loading,0.34 g/L of H2O2 concentration and 11 W low mercury light to 50 mg/L GTL-containing simulated wastewater.Degradation pathways include de-auxochrome,cleavage of azo bond,formation of benzene ring and small molecular compounds alcohol,aldehyde,further degradation of intermediate products to low molecular weight organic acid.The final products are Cl-,NO3-,SO42-,CO2 and water." @default.
- W2388423556 created "2016-06-24" @default.
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- W2388423556 date "2008-01-01" @default.
- W2388423556 modified "2023-09-23" @default.
- W2388423556 title "Oxidation degradation of cationic red GTL by photo-Fenton" @default.
- W2388423556 hasPublicationYear "2008" @default.
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