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- W2388458051 abstract "The metastable phase equilibrium of the quaternary system Na+Cl-, CO32-, B4O72-H2O was studied at 273 K by isothermal evaporation method, the solubility and density of the equilibrium solution of this system were determined and the metastable equilibrium phase diagram was plotted in line with the experimental data. The phase diagram of the system consists of three univariant curves, three crystallization fields and one invariant point. This system is of eutectic type, no double salt or solid solution was formed. The four crystallization fields were corresponding to single salt Na2CO3·10H2O, NaCl and Na2B4O7·10H2O, respectively. Invariant point E was saturated with salts Na2CO3·10H2O, NaCl and Na2B4O7·10H2O, the mass fraction composition of the equilibrium solution corresponding to E is w(Na2CO3)=6.81%, w(NaCl)=21.69%, w(Na2B4O7)=0.65%, w(H2O)=70.85%. The Na2CO3·10H2O is the only crystal form of the salt sodium carbonate in this system at 273 K. Na2B4O7 has salting out effect to Na2CO3 in the solution." @default.
- W2388458051 created "2016-06-24" @default.
- W2388458051 creator A5072777154 @default.
- W2388458051 date "2008-01-01" @default.
- W2388458051 modified "2023-09-23" @default.
- W2388458051 title "METASTABLE PHASE EQUILIBRIUM OF THE QUATERNARY SYSTEM Na~+∥Cl~-,CO_3~(2-),B_4O_7~(2-)-H_2O AT 273K" @default.
- W2388458051 hasPublicationYear "2008" @default.
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