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- W2388587002 abstract "The standard molar enthalpy of formation,the standard entropy and isobaric molar heat capacity of Fischer-Tropsch syncrude were estimated by Benson group contribution method and ABWY method. The enthalpy change,Gibbs free energy change and equilibrium constant of hydrocracking and isomerization reaction of FischerTropsch syncrude were calculated as a function of the temperature from 298 K to 750 K. The thermodynamic possibility and formation sequences of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude were judged. Meanwhile,the thermodynamic equilibrium and the limit of different reaction steps were also analyzed. The results show that the hydrocracking and isomerization reaction of Fischer-Tropsch syncrude is an exothermic reaction,most of which are spontaneous at low temperature and can reach to a deep extent. Improving the temperature is not good for hydrocracking and isomerization reaction from a thermodynamic point of view. The choice of the suitable temperature should take into account all the reactions. The occurrence of the hydrocracking and isomerization reaction of alkene is easier than that of alkane. The thermodynamic data obtained can provide the theoretical basis for the study of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude process, reactor development and new catalyst preparation." @default.
- W2388587002 created "2016-06-24" @default.
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- W2388587002 date "2014-01-01" @default.
- W2388587002 modified "2023-09-25" @default.
- W2388587002 title "Thermodynamics of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude" @default.
- W2388587002 hasPublicationYear "2014" @default.
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