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- W2388631191 abstract "The ultrasonic degradation of p-dichlorobenzen(p-DCB)in aqueous solution was studied,and the effect of influence factors on reaction kinetics was investigated.The results showed that the sonolysis process followed the apparent first order kinetics,and the reaction rate constant decreased with increasing the initial p-DCB concentration.The degradation of p-DCB was promoted by increasing intensity and frequency of ultrasonic,and acidulous or neutral conditions were favorable for the degradation of p-DCB.Stirring and butanol weakened the thermal cracking and decreased ·OH radical content in cavitation bubbles and thus retarded p-DCB degradation.Ultrasonic degradation of p-DCB was easier than that of p-chloroaniline(p-ClA)in single degradation system.In the mixture system of p-DCB and p-ClA,the sonolysis rate of p-DCB was not significantly influenced by p-ClA,because p-ClA was nonvolatile and hydrophilic,and it was difficulity for p-ClA to compete the energy and ·OH radical in cavitation bubbles.While the presence of p-DCB decreased the p-ClA sonolysis rate obviously for hydrophobic p-DCB was easy to enter into cavitation bubbles for energy and ·OH radical competition and then decreased the specific heat of mix gas." @default.
- W2388631191 created "2016-06-24" @default.
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- W2388631191 date "2010-01-01" @default.
- W2388631191 modified "2023-09-24" @default.
- W2388631191 title "Study on ultrasonic degradation of p-dichlorobenzen in aqueous solutions" @default.
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