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- W2388894107 abstract "2(3),9(10),16(17),23(24)-tetra-(4-phenylimine phenoxy) phthalocyanine zinc(Ⅱ)(C84H52N12O4Zn)(APc) and 2(3)-(2-methyl-8-quinolinoxy)-9(10),16(17),23(24)-tri-(4-phenylimine phenoxy phthalocyanine zinc(Ⅱ)(C81H50N12O4Zn)(BPc) were synthesized from 4-hydroxybenzaldehyde and characterized by means of UV-Vis,IR,1HNMR spectra and elemental analysis.The aggregative behavior was studied in DMF by UV-Vis.The results show that BPc is not aggregative in DMF.However,APc is aggregative in DMF at the concentration of 1.499 × 10-5mol / L ~ 2.407 × 10-5mol / L.The Q-band maximum absorption peaks of APc and BPc appear at 672 nm and 676 nm,which,compared with the unsubstituted zinc phthalocyanine(669 nm),obviously have red shift.The electrochemical properties and energy band structure are studied by cyclic voltammetry.They have low LUMO(-5.411 eV,-5.384 eV) and a deep HOMO(-4.214 eV,-4.210 eV) energy level.It is indicated that APc and BPc matches with the energy level of the nanocrystalline of TiO2." @default.
- W2388894107 created "2016-06-24" @default.
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- W2388894107 date "2014-01-01" @default.
- W2388894107 modified "2023-09-28" @default.
- W2388894107 title "Synthesis of Schiff Base Zinc Phthalocyanines and Properties" @default.
- W2388894107 hasPublicationYear "2014" @default.
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