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- W2388896251 abstract "Temperature Programmed Pulse Reaction (TPPR) teclmique wasemployed to investigate the oxygen mobility and reactivity of Ceria-basedCe/Sr catalysts for oxidative coupling of methane. Based on the results, theoxygen adsorbing ability and mobility of the involved catalysts could bearranged in the order of CexCe/SrSrCO3. The Oxygen mobility wasexplained and modeled by the diffusion mechanism of subsurface and bulklattice oxygen in terms of lattice defects. The result of CH4 TPPR indicatedthat the adsorbed oxygen species are more reactive than the surface latticeones including those generated from the diffusion of bulk oxygen ions. Onthe Ce/Sr composite catalyst two active sites are expected to take pat in theselective oxidation of methane. One is the oxygen intermediates from theadsorption of gas phase oxygen, the other is the strong basic SrO(s) sitesfrom the decomposition of SrCO3." @default.
- W2388896251 created "2016-06-24" @default.
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- W2388896251 date "1997-01-01" @default.
- W2388896251 modified "2023-09-26" @default.
- W2388896251 title "STUDY ON THE MOBILITY AND REACTIVITY OF OXYGEN OF CERIA-BASED OCM CATALYSTS BY TEMPERATURE PROGRAMMED PULSE REACTION(TPPR)" @default.
- W2388896251 hasPublicationYear "1997" @default.
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