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- W2389221425 abstract "Irradiation effects on chlorinated polyethylene(CPE) were studied by 1D and 2D NMR spectroscopy,measurements of proton spin-spin relaxation time(T2) and spin-lattice relaxation time(T1) and FT-IR.The results indicated that degradation reactions took place after CPE was irradiated by 60Co γ-rays.It was shown that HCl emitted during irradiation.The higher the absorbed doses was,the more HCl emitted.The quantity of some sequential structures(e.g.,CH2CHClCHClCH2CHCl,CH2CH2CHClCH2CH2,CHClCH2CHClCH2CH2, and CHClCH2CHClCH2CHCl) of CPE were found reduced after irradiation,but there were no evidence indicating that new sequential structures were formed.The values of T1 and T2 also provided very important information about the segmental motion of the molecules." @default.
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- W2389221425 date "2008-01-01" @default.
- W2389221425 modified "2023-09-23" @default.
- W2389221425 title "Irradiation Effects on Chlorinated Polyethylene Studied by NMR Spectroscopy" @default.
- W2389221425 hasPublicationYear "2008" @default.
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