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- W2389402870 abstract "diformylfuran (DFF) is one of the important platform molecules derived from 5-hydroxymethyl- furfural (HMF) or other bio-based carbohydrates, which has lots of potential applications in many fields of organic synthesis industry. This compound has become a research focus in recent years due to its relatively high price and immature synthesis technology. To realize the industrial pro- duction of DFF in the future, many methods have been attempted to achieve this product efficient- ly. In this research, some transition metal compounds and lanthanides, including Nb2O5, V2O5, C3F9O9S3Yb·xH2O, Na3VO4, KVO3 and MnO2, were adopted as plausible high-efficiency catalysts in aerobic oxidation of biomass-derived model molecule 5-Hydroxymethylfurfural (HMF) with the purpose of achieving high value-added DFF. The results from gas chromatographic analysis (GC) and gas chromatography-mass spectrometer (GC-MS) showed that Nb2O5 and Na3VO4 seem to have no obvious catalytic activity in this reaction. Moreover, no DFF was formed with C3F9O9S3Yb·xH2O and MnO2, other oxidation products such as 5-acetoxymethyl-2-furaldehyde were formed; KVO3 and V2O5 were found to be efficient catalysts for the aerobic selective oxidation reaction from HMF to DFF." @default.
- W2389402870 created "2016-06-24" @default.
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- W2389402870 date "2014-01-01" @default.
- W2389402870 modified "2023-09-27" @default.
- W2389402870 title "Transition Metal Compounds as Efficient Catalysts in Aerobic Oxidation of Biomass-Derived 5-Hydroxymethylfurfural to 2,5-Diformylfuran" @default.
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